Abstract We present a reconstruction of the chronological sequence of events that took place during the first days of the 2012–2013 Tolbachik fissure eruption using petrological data and remote sensing methods. We were forced to use this approach because bad weather conditions did not allow direct observations during the first two days of the eruption. We interpreted infrared images from the scanning radiometer {VIIRS} Suomi {NPP} and correlated the output with the results of the geochemical study, including comparison of the ash, deposited at the period from 27 to 29 November, with the samples of lava and bombs erupted from the Menyailov and Naboko vents. We argue that the compositional change observed in the eruption products (the decrease of SiO2 concentration and K2O/MgO ratio, increase of MgO concentration and Mg#) started approximately 24 h after the eruption began. At this time the center of activity moved to the southern part of the fissure, where the Naboko group of vents was formed; therefore, this timeframe also characterizes the timing of the Naboko vent opening. The Naboko group of vents remained active until the end of eruption in September 2013.