The numerous of national and international publications were dedicated to Plosky Tolbachik volcano eruptions and adjacent monogenetic cones, which were erupted repeatedly during Holocene, including historical time [i.e. Vlodavets, 1937; Popkov, 1946; Peep, 1946, 1954; Menyailov, 1953; Sirin and Farberov, 1963; Kirsanov et al., 1974; Ivanov and Khrenov, 1979; Fedotov, 1984; Krivenko, 1990; Kersting, 1995; Tatsumi et al., 1995; Hochstaedter et al., 1996; Kepezhinskas et al., 1997; Turner et al., 1998; Pineau et al., 1999; Volynets et al., 2000; Churikova et al., 2001; Münker et al., 2004; Portnyagin et al., 2007; Volynets et al., 2013]. However, all these data mainly relates to monogenetic cones, but the information on stratovolcanoes itself practically absent. There are only few papers on Ostry and Plosky Tolbachik stratovolcanoes focusing on geology [Ermakov and Vazheevskaya, 1973], petrography and some petrochemistry of the rocks [Ermakov, 1977; Flerov and Melekestsev, 2013]. The modern geochemical and isotope studies of the stratovolcanoes were never achieved. In this report we present geological, petrographical, petrochemical, geochemical and some K-Ar data on the rocks of Tolbachik massif. The present report based on representative collection of 154 samples from stratovolcanoes, dikes, monogenetic cones of different ages, including last 2012-2013 eruption. Additionally our study included samples separately standing edifice of Povorotnaya mount, which age according to K-Ar dating is 0.306±0.01 Ма.